Study Aid – How to compute the photon energy in eV, given wavelength in nm.
Recall that the photon energy is given by E = hf = hc/(wavelength). Calculating the energy in joules is easy enough, but often it is useful to be able quickly to compute the energy in eV directly by knowing the wavelength in nm. The conversion from joules to eV is done by dividing by 1.6 x 10-19 J/eV. The transformation from meters to nanometers is accomplished by expressing wavelength in nm and multiplying by the factor 10 -9.
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Since the difference in energy between levels is 0.293 eV, the wavelength of the emitted photon when the molecule falls to the next lowest vibrational level is 1240/0.293 = 4232 nm. This radiation is in the infrared.
The de Broglie wavelength of a particle of mass m, moving at
a speed v is h/mv, where h is Planck’s constant.
But the wavelength is also given in general by wavelength = v/frequency.
Thus,
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Substituting
the numbers gives
v2 = (6.63 x 10-34 Js)(5.0 x 1012
Hz)/(9.11 x 10-31 kg) = 36.4 x 108 m2/s2,
or v = 6.0 x 104 m/s.