Radial Schrodinger Equation

For a potential which only depends on the magnitude of r, |r|, the operators L2 and Lz commute with the hamiltonian. The stationary states of the Schrodinger equation may thus be taken to be eigenvectors of L2 and Lz as well. Writing the solution as psi(r,theta,phi) = R(r)Ylm(theta,phi), the function R(r) obeys a radial Schrodinger equation. It is customary to write R(r)=u(r)/r, where the function u(r) can be shown to obey the one dimensional Schrodinger equation for r>0 with an effective potential energy equal to the original potential energy plus a term due to the kinetic energy in the theta and phi directions. For small r, u(r) behaves like rl+1 so u(0) = 0.