Hydrogen Atom

When the radial Schrodinger equation for the hydrogen atom is written in dimensionless form, the natural length and energy scales to emerge are the Bohr radius, ao, (0.52 Angstroms; 1 Angstrom = 10-10m) and the Rydberg, EI (13.6 eV), respectively. Asymptotically, the function u(r) decays exponentially at large distances for energies less than zero. Solving the differential equation by a series solution, the normalizable solutions for u(r) are polynomials times the exponentially decaying factor. These solutions are only valid at certain energies E = -EI/n2 for n= 1, 2, 3, ... At other energies less than zero, the solutions to the radial Schrodinger equation grow exponential at infinity.