W. Gregory Sawyer - TRIBOLOGY IS
COMPACTLY defined by the Oxford English Dictionary as "the branch
of science concerned with
interacting surfaces in relative motion and with associated matters
(as friction, wear, lubrication, and the design of bearings." Friction
and wear are not intrinsic properties of a material; they are functions
of the tribological system. A tribological system is composed of three
basic elements, (1) the structure - the types of materials in contact
and the contact geometry, (2) the operating conditions - the gross motion,
loads, stresses, and duration of operation, and (3) the environment
and surface conditions - including the surface environment and chemistry,
surface topography, and ambient temperature. The shear number of factors
affecting performance makes fundamental studies exceedingly difficult.
The studies that aim to explore these fundamentals within a tribology
framework generally focus on the mechanisms of friction and the mechanisms
of wear.
When two bodies are in contact and relative
motion, a finite force is required to maintain this motion, the friction
force . A coefficient of friction is calculated by dividing the friction
force by the normal force. To date, despite considerable efforts, there
is no model capable of predicting friction coefficients from first principles.
Thus, careful and proven experimental techniques represent the most
sophisticated and reliable technique for investigating, designing, and
assessing the tribological worthiness of new materials. The tribological
system must be defined well in advance of an experimental study in friction.
The three basic points that are considered fundamental to studies of
friction are the surface area and nature of the intimate asperity contacts,
the surface adhesion and shear strength, and the nature of deformation
and energy dissipation occurring at the asperity junctions.
Wear is the gradual removal of material from
contacting surfaces in relative motion. Analogous to the mechanisms
of friction, there are four basic wear modes that are used in the classification
of wear: (1) adhesive wear, (2) abrasive wear, (3) surface fatigue wear,
and (4) tribochemical wear. In adhesive wear, the junctions that give
rise to the resistance to sliding can also cause removal of discrete
particles at the asperity junctions. Abrasive wear is similar to the
plowing contribution of friction; the plastic deformation creates wear
debris that is eventually ejected from the contact. In surface fatigue
wear and delamination, a variety of cyclic events initiates and propagates
cracks. The cracks eventually become large enough to cause discrete
regions near the surface to be ejected as debris. Tribochemical wear
mechanisms involve a coupling between the mechanical and thermal processes
occurring at the interface and the environment. Here the corrosiveness
or reactivity of the environment is generally enhanced due to these
mechanical and thermal processes.